@Chad: Glad to be of service.
As for the attachments... The guitar hero grip actually uses the GBA hardware. It registers the button presses by watching for several of the GBA cart data line to be pulled to ground. Emulating it would take an enormous amount of work, and with HLE, it would be near impossible. A lot of people are saying "oh m gee just use teh keyboard" but the problem is not figuring out a way to interface the emulator to the Pandora; it is getting the emulator to talk to the game. These are not normal button press calls like most emulators watch for, they are hardware specific functions. In addition, this would wipe out the possibility of porting an exsisting NDS emu, as none of them use the correct approach to handle these add ons.
One more thing: Face training camera=/ USB camera. It is another one of those devices that uses a special, proprietary, closed source transfer format. Interfacing a USB camera to it would be impossible.
Same with most of the other attachments: The odds of being able to emulate them is next to NOTHING. So get rid of all hope for them, and get back with the real discussion: OMG so I liek herd the Pandora2X can emulate DS at launch cuz Exo promised? Tat is teh PWNZR!
One more thing, God Ginrai: The Pandora screen is not multi touch. I believe you would be somewhat disappointed when you realize that you would not be able to press the chords and strum at the same time.