Update (small):
Ok, case painted with 2 coats so far, looks quite nice. Needs quick sanding and another coat yet. More on that later.
I experimented with soldering wires to an old board I had, placing a drop of solder onto each button contact, soldering a wire to it, and testing. This worked fine, all be it that the solder joint was not strong enough, but that could have been strengthened by hot-glue too. I then tried this on the GP2x motherboard, but the solder refused to stick to the board. I tried a few times, no luck. It has a similar adhesion to toothpaste!
I then decided I had no option (as solder is an issue) of using hot glue. I could have bought some solder tracer, but there is no guarantee that it would work, and it costs £19.99 from Maplin (far too expensive for a mod).
Problem with using hot glue is that you only have a very, very tiny contact area between a wire and the motherboard - literally a tip. This means that it is a fine line between making a contact and not making contact. Once you make contact, you then need to smother the area with more hot glue to stop the wire moving. Quite touch and go, and takes a lot of time to get it right.
Other problem with doing this method is that you need to have the GP2x on, in T-mode, so you know if a wire is connected correctly while you are gluing the area. Basically, you have an external battery pack connected to the GP2x, with everything laid exposed on the board. You have to be careful not to damage the LCD screen cable, and there is a risk of damaging the GP2x (as power is on) while your fingers move around the motherboard manouvering the wires to connect to the buttons. This is not ideal; and if my GP2x stops working (short-circuit?) and dies, this project will terminate and all the work I have done so far on this project will cease.
So far, I have got one button connected to two wires successfully on the GP2x, lots of hot-glue - but fine; seven more to go - seven more chances to blow the motherboard!
Time for sod's law now, now I have said this, I am sure it will go tits up and my GP2x will blow! <_< ... here goes...